Here are the songs that debuted in the anime series based on the Nintendo 3DS games Pocket Monsters X and Pocket Monsters Y.

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Opening Themes
Here are the Japanese openings for the fifth Pocket Monsters TV series.

Title	Description	Symbols
V(ボルト) (V (Volt))	The first opening theme to the series.  TV size.
V(ボルト) (V (Volt))	The full version of the first opening theme.
メガV (メガボルト) (Mega V (Mega Volt))	The second opening theme to the series.  TV size.
メガV (メガボルト) (Mega V (Mega Volt))	The full version of the second opening theme.

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Ending Themes
Here are the Japanese endings for the fifth Pocket Monsters TV series.
 

Title	Description	Symbols
X海峡Y景色 (X Strait Y Scenery)	The first version of the first ending theme.  TV size.	-
メガV (メガボルト) (Mega V (Mega Volt))	The ending theme to the Pocket Monsters XY TV Special "The Greatest Mega Evolution ~ Act I ~."  TV size.
ピー ズスマイル (Peace Smile)	The second ending theme.  TV size.

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Songs from the Movies
Here are the Japanese songs used in the various Pocket Monsters XY theatrical movies.
 

Title	Description	Symbols
メガV (メガボルト) (Mega V (Mega Volt))	The opening theme to The Cocoon of Destruction and Diancie.  TV size.
夜明 けの流星群 (The Early Morning Meteor Shower)	The ending theme to The Cocoon of Destruction and Diancie.	-
ピー ズスマイル (Peace Smile)	The opening theme to Pikachu, What is This the Key To?  TV size