To celebrate the franchise's ten-year anniversary, Viz released two sets of ten "best of" DVDs, each one focusing on a different pokemon.  The pokemon being showcased were selected by fans via the Pokemon.com website.

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Region One:  Indigo League | Adventures in the Orange Islands Johto Journeys | Johto League Champions | Master Quest Advanced | Advanced Challenge | Advanced Battle | Battle Frontier Diamond & Pearl | DP Battle Dimension | DP Galactic Battles | DP Sinnoh League Victors Black & White | BW Rival Destinies | BW Adventures in Unova (and Beyond) Movies & Specials | Tenth Anniversary | Elements Region Two:  TV Episodes | Movies & Pikachu Shorts | Pikachu The Movie Box TV Specials & ANA Shorts | Theme Song Collections Region Two Best Collection:  Pocket Monsters | Pocket Monsters Diamond & Pearl Pocket Monsters Best Wishes! + Pocket Monsters

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Individual Discs

 

Volume One:  Pikachu Number of Discs:  1 Released June 6th, 2006 Contains Episodes 101, 136, and 214 "Pokmon - I Choose You!" "Pikachu's Goodbye" "The Pi-Kahuna" Order it now on Amazon.com

 

Volume Two:  Jigglypuff Number of Discs:  1 Released June 6th, 2006 Contains Episodes 142, 205, and 229 "The Song of Jigglypuff" "Beach Blank-Out Blastoise" "A Scare in the Air" Order it now on Amazon.com

Volume Three:  Charizard Number of Discs:  1 Released August 22nd, 2006 Contains Episodes 143, 252, and 329 "Attack of the Prehistoric Pokémon" "Charizard Chills" "Charizard's Burning Ambitions" Order it now on Amazon.com

Volume Four:  Squirtle Number of Discs:  1 Released August 22nd, 2006 Contains Episodes 112, 117, and 232 "Here Comes the Squirtle Squad" "Island of the Giant Pokémon" "Fit to be Tide" Order it now on Amazon.com

Volume Five:  Blastoise Number of Discs:  1 Released October 24th, 2006 Contains Episodes 607, 608, and 752 "The Ties That Bind" "Can't Beat the Heat!" "Judgment Day!" Order it now on Amazon.com

Volume Six:  Eevee Number of Discs:  1 Released October 24th, 2006 Contains Episodes 137, 311, and 426 "The Battling Eevee Brothers" "The Rivalry Revival" "Trouble's Brewing" Order it now on Amazon.com

Volume Seven:  Bulbasaur Number of Discs:  1 Released October 24th, 2006 Contains Episodes 110, 148, and 516 "Bulbasaur and the Hidden Village" "Bulbasaur's Mysterious Garden" "Bulbasaur, the Ambassador!" Order it now on Amazon.com

Volume Eight:  Lugia Number of Discs:  1 Released  December 5th, 2006 Contains Episodes 511-513 "The Mystery is History" "A Parent Trapped" "A Promise is a Promise" Order it now on Amazon.com

Volume Nine:  Charmander Number of Discs:  1 Released December 19th, 2006 Contains Episodes 111, 211, and 140 "Charmander - The Stray Pokémon" "Snow Way Out!" "The March of the Exeggutor Squad" Order it now on Amazon.com

Volume Ten:  Mudkip Number of Discs:  1 Released December 19th, 2006 Contains Episodes 637, 638, and 617 "A Mudkip Mission!" "Turning Over a Nuzleaf!" "In the Knicker of Time" Order it now on Amazon.com

Volume Eleven:  Meowth Number of Discs:  1 Released October 28th, 2008 Contains Episodes 202, 217, and 243 "The Purr-fect Hero" "Go West, Young Meowth" "Meowth Rules!" Order it now on Amazon.com

Volume Twelve:  Treecko Number of Discs:  1 Released October 28th, 2008 Contains Episodes 619, 620, and 701 "Tree's A Crowd" "A Tail With A Twist" "What You Seed Is What You Get" Order it now on RightStuf.com

Volume Thirteen:  Psyduck Number of Discs:  1 Released October 28th, 2008 Contains Episodes 131, 216, and 238 "The Ninja Poké-Showdown" "Lights, Camera, Quack-tion!" "Bye Bye Psyduck" Order it now on Amazon.com

Volume Fourteen:  Wobbuffet Number of Discs:  1 Released October 28th, 2008 Contains Episodes 416, 435, and 821 "Wobbapalooza" "The Wayward Wobbuffet" "Who, What, When, Where, Wynaut?" Order it now on Amazon.com

Volume Fifteen:  Lapras Number of Discs:  1 Released December 16th, 2008 Contains Episodes 231, 308, and 547 "The Lost Lapras" "Viva Las Lapras" "Lapras of Luxury" Order it now on Amazon.com

Volume Sixteen:  Totodile Number of Discs:  1 Released December 16th, 2008 Contains Episodes 312, 346, and 348 "Don't Touch That 'dile" "The Totodile Duel" "Love, Totodile Style" Order it now on Amazon.com

Volume Seventeen:  Skitty Number of Discs:  1 Released February 17th, 2009 Contains Episodes 707, 713, and 829 "I Feel Skitty!" "Game Winning Assist" "Deceit and Desist" Order it now on Amazon.com

Volume Eighteen:  Chikorita Number of Discs:  1 Released February 17th, 2009 Contains Episodes 321, 331, and 442 "Chikorita Rescue" "Chikorita's Big Upset" "Current Events" Order it now on Amazon.com

Volume Ninteen:  Torchic Number of Discs:  1 Released April 21st, 2009 Contains Episodes 617, 646, and 742 "In the Knicker of Time" "Having a Wailord of a Time" "A Shroomish Skirmish" Order it now on Amazon.com

Volume Twenty:  Onix Number of Discs:  1 Released April 21st, 2009 Contains Episodes 105, 218, and 844 "Showdown in Pewter City" "To Master the Onixpected" "Hooked on Onix" Order it now on Amazon.com

Box Sets

Pokémon Top Ten (aka Pokémon All-Stars Collection) Number of Discs:  10 Released May 22nd, 2007 Contains Episodes 101, 136, 214, 229, 142, 205, 229, 142, 205, 229, 143, 252, 329, 112, 117, 232, 607, 608, 752, 137, 311, 426, 110, 148, 516, 511-513, 111, 211, 140, 637, 638, and 617 Disc One "Pokmon - I Choose You!" "Pikachu's Goodbye" "The Pi-Kahuna" Disc Two "The Song of Jigglypuff" "Beach Blank-Out Blastoise" "A Scare in the Air" Disc Three "Attack of the Prehistoric Pokémon" "Charizard Chills" "Charizard's Burning Ambitions" Disc Four "Here Comes the Squirtle Squad" "Island of the Giant Pokémon" "Fit to be Tide" Disc Five "The Ties That Bind" "Can't Beat the Heat!" "Judgment Day!" Disc Six "Battling Eevee Brothers" "The Rivalry Revival" "Trouble's Brewing" Disc Seven "Bulbasaur and the Hidden Village" "Bulbasaur's Mysterious Garden" "Bulbasaur, the Ambassador!" Disc Eight "The Mystery is History" "A Parent Trapped" "A Promise is a Promise" Disc Nine "Charmander - The Stray Pokémon" "Snow Way Out!" "The March of the Exeggutor Squad" Disc Ten "A Mudkip Mission!" "Turning Over a Nuzleaf!" "In the Knicker of Time" Order it now on Amazon.com

Pokémon All-Stars Box Set 2 Number of Discs:  10 Released August 25th, 2009 The following episode listing is an educated guess only.  The disc's contents have not officially been announced yet and are therefore subject to change. Contains Episodes 207, 217, 243, 619, 620, 701, 131, 216, 238, 416, 435, 821, 231, 308, 547, 312, 346, 348, 707, 713, 829, 321, 331, 442, 617, 646, 742, 105, 218, and 844 Disc One "The Purr-fect Hero" "Go West, Young Meowth" "Meowth Rules!" Disc Two "Tree's A Crowd" "A Tail With A Twist" "What You Seed Is What You Get" Disc Three "The Ninja Poké-Showdown" "Lights, Camera, Quack-tion!" "Bye Bye Psyduck" Disc Four "Wobbapalooza" "The Wayward Wobbuffet" "Who, What, When, Where, Wynaut?" Disc Five "The Lost Lapras" "Viva Las Lapras" "Lapras of Luxury" Disc Six "Don't Touch That 'dile" "The Totodile Duel" "Love, Totodile Style" Disc Seven "I Feel Skitty!" "Game Winning Assist" "Deceit and Desist" Disc Eight "Chikorita Rescue" "Chikorita's Big Upset" "Current Events" Disc Nine "In the Knicker of Time" "Having a Wailord of a Time" "A Shroomish Skirmish" Disc Ten "Showdown in Pewter City" "To Master the Onixpected" "Hooked on Onix" Order it now on Amazon.com